Redox Reaction Accelerated by Solvent Freezing
نویسندگان
چکیده
منابع مشابه
Solvent, Ligand, and Ionic Charge Effects on Reaction Entropies for Simple Transition-Metal Redox Couples
The dependence of the reaction entropies, ASo,, for simple M(III/II) redox couples (M = Ru, Fe, Os, Cr) upon the nature of the ligands and the solvent is examined with a view toward correlating ASo, with simple physical parameters. For couples containing ammine, ethylenediamine, polypyridine, cyclopentadiene, or pseudohalide ligands, ASo, in a given solvent is found to correlate well with (Zo: ...
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Solvent effects on the rates of some well-known nuclophilic substitution reactions have been analysed in terms of initial—state and transition-state contributions. Where possible, the latter have been further analysed by the method of model solutes, on which solvent effects on a transition state are compared to solvent effects on a solute that might be a suitable model for the transition state....
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ژورنال
عنوان ژورنال: Journal of Computer Chemistry, Japan
سال: 2010
ISSN: 1347-3824,1347-1767
DOI: 10.2477/jccj.h2203